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2-Bromo-5-nitrothiophene

  • Name 2-Bromo-5-nitrothiophene
  • CAS 13195-50-1
  • Purity 99%
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Product Details

High Quality Chinese Factory supply 13195-50-1 2-Bromo-5-nitrothiophene

  • Molecular Formula: C4H2BrNO2S
  • Molecular Weight: 208.035
  • Appearance/Colour: white to light yellow crystal powder 
  • Vapor Pressure: 0.0295mmHg at 25°C 
  • Melting Point: 44-48 °C(lit.) 
  • Refractive Index: 1.647 
  • Boiling Point: 253.2 °C at 760 mmHg 
  • Flash Point: 106.9 °C 
  • PSA: 74.06000 
  • Density: 1.945 g/cm3 
  • LogP: 2.94200 

2-Bromo-5-nitrothiophene(Cas 13195-50-1) Usage

General Description

2-Bromo-5-nitrothiophene is a heteroaryl halide that can be prepared from thiophene by bromination followed by nitration. It participates in the synthesis of oligothiophene precursors for generating (porphinato)zinc(II)-based chromophores.

InChI:InChI=1/C4H2BrNO2S/c5-3-1-2-4(9-3)6(7)8/h1-2H

13195-50-1 Relevant articles

Studies on the biological activity of some nitrothiophenes

Morley, John O.,Matthews, Thomas P.

, p. 359 - 366 (2006)

The biological activity of nineteen subs...

INVESTIGATION OF THE KINETICS OF THE NITRATION OF THIOPHENE DERIVATIVES

Freidlin, G. N.,Glushkova, A. A.,Solop, K. A.

, p. 127 - 130 (1982)

The kinetics of the nitration of thiophe...

-

Babasinian

, p. 1763 (1935)

-

Synthesis, transition temperatures, and optical properties of various 2,6-disubstituted naphthalenes and related 1-benzothiophenes with butylsulfanyl and cyano or isothiocyanato terminal groups

Seed,Toyne,Goodby,Hird

, p. 2069 - 2080 (2007/10/03)

Fourteen compounds based on 2,6-disubsti...

Anisotropic organic compounds

-

, (2008/06/13)

STR1 The invention describes liquid crys...

Naphthyl organic compounds

-

, (2008/06/13)

Liquid crystal compounds of formula (I) ...

13195-50-1 Process route

2-nitrothiophene
609-40-5

2-nitrothiophene

bromine
7726-95-6

bromine

2-bromo-5-nitrothiophene
13195-50-1,76216-72-3

2-bromo-5-nitrothiophene

2,3-dibromo-5-nitro-thiophene
40492-18-0

2,3-dibromo-5-nitro-thiophene

Tetrabromothiophene
3958-03-0

Tetrabromothiophene

Conditions
Conditions Yield
2-bromothiophene
1003-09-4

2-bromothiophene

2-bromo-5-nitrothiophene
13195-50-1,76216-72-3

2-bromo-5-nitrothiophene

Conditions
Conditions Yield
With nitric acid; acetic anhydride; at 0 ℃;
66%
With nitric acid; acetic anhydride; at -5 ℃;
31%
With nitric acid; acetic anhydride; at -14 ℃; Kinetics; Rate constant; Thermodynamic data; other temperatures, E, lg A, ΔH(excit.), ΔS(excit.);
With nitric acid; acetic anhydride;
With nitric acid;

13195-50-1 Upstream products

  • 1003-09-4
    1003-09-4

    2-bromothiophene

  • 609-40-5
    609-40-5

    2-nitrothiophene

  • 7726-95-6
    7726-95-6

    bromine

13195-50-1 Downstream products

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    2-acetylaminothiophene

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    5,5'-diacetyldiamino-2,2'-dithienyl

  • 13195-53-4
    13195-53-4

    2-nitro-5-phenylsulfanyl-thiophene

  • 79929-25-2
    79929-25-2

    5-nitro-2-thienyl-4'-nitrophenylsulfide

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